Preheat smoker to 250-275° F (121° to 135° C) using desired wood for smoke flavor, such as oak, pecan or apple.
Make the Chili Base
Wearing nitrile gloves, slice the chili peppers and remove seeds and pith. Chop peppers into 1/2" pieces.
In a large Dutch oven over medium heat, melt the butter. Add onions and a pinch of salt. Sauté until onions are soft and translucent, 5-7 minutes.
Add the chopped peppers and cook for 1 minute.
Stir in tomato paste and cook for 1 minute, then add the diced tomatoes, drained beans, chicken stock, Worcestershire, soy sauce, chili powder, cumin, cayenne, and sugar. Bring to a simmer.
Optional: Transfer chili base to a disposable aluminum baking dish for easier cleanup.
Make the Meat Loaf
While the chili base is on the stove, gently combine ground beef, salt, pepper, chili powder, and smoked paprika in a bowl. Form it into an elongated oval-shaped loaf. Lightly coat with oil and sprinkle with a barbecue rub if desired.
Place a wire rack over chili base. Set the meatloaf on rack so drippings fall into the chili base. Insert a remote probe meat thermometer into the thickest part of the meat.
Smoke and Finish the Chili
Place in the smoker and cook for 2-2.5 hours until meat thermometer reaches 150° F.
Increase smoker heat to 350°F and continue to cook until the internal temperature reaches 155°F, about 5 to 10 minutes more.
Remove the meat loaf from the smoker and let rest for 5 to 10 minutes before crumbling.
Crumble rested meat loaf into chili base and stir to combine.
Return to the smoker and cook for 30 minutes to 1 hour until thickened to desired consistency.
Taste and season with more salt, sugar, or spices as desired.
Serve with desired toppings or cool and refrigerate to serve the next day.
Notes
Use a smoke tube for extra smoke flavor if using a pellet grill.
Cooking directly in pots/pans can leave smoke residue. Use a disposable aluminum pan or plain cast iron Dutch oven for easy cleanup.
You can use half ground pork and half ground beef for the meat loaf.
Spoon off excess fat from the top for less richness, if desired. The fat adds flavor but can be removed to taste.